Giải bài 3 trang 132 SGK Hóa học 11

Viết phương trình hóa học của phản ứng xảy ra khi;
a) Propilen tác dụng với hidro, đun nóng (xúc tác Ni ).
b) But-2-en tác dụng với hidro clorua.
c) Metylpropen tác dụng với nước có xúc tác axit.
d) Trùng hợp but-1-en.
Lời giải:

\(\begin{align} & a)\,C{{H}_{2}}=CH-C{{H}_{3}}+{{H}_{2}}\xrightarrow{{{t}^{o}},\,Ni}C{{H}_{3}}-C{{H}_{2}}-C{{H}_{3}} \\ & b)\,C{{H}_{3}}-CH=CH-C{{H}_{3}}+HCl\to C{{H}_{3}}-C\underset{\left| {} \right.}{\mathop{H}}\,-C{{H}_{2}}-C{{H}_{3}} \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Cl \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,OH \\ & c)\,C{{H}_{2}}=\underset{\left| {} \right.}{\mathop{C}}\,-C{{H}_{3}}+{{H}_{2}}O\xrightarrow{{{H}^{+}}}C{{H}_{3}}-\underset{\left| {} \right.}{\overset{\left| {} \right.}{\mathop{C}}}\,-C{{H}_{3}} \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\ & d)\,nC{{H}_{2}}=CH-C{{H}_{2}}-C{{H}_{3}}\xrightarrow{{{t}^{o}},xt,p}{{(-C{{H}_{2}}-\underset{\left| {} \right.}{\mathop{CH}}\,-)}_{n}} \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,{{C}_{2}}{{H}_{5}} \\ \end{align} \)