Giải bài 1 trang 145 SGK Hoá học 11

a) Viết công thức cấu tạo và gọi tên các ankin có công thức C4H6 và C5H8.
b) Viết công thức cấu tạo của các ankin có tên sau: pent-2-in ; 3-metylpent-1-in; 2,5- đimetylhex-3-in
Lời giải:

\(\begin{align} & a){{C}_{4}}{{H}_{6}}: \\ & \_\,CH\equiv C-C{{H}_{2}}-C{{H}_{3}}\,(but-1-in) \\ & \_\,C{{H}_{3}}-C\equiv C-C{{H}_{3}}\,(but-2-in) \\ & {{C}_{5}}{{H}_{8}}: \\ & \_\,CH\equiv C-C{{H}_{2}}-C{{H}_{2}}-C{{H}_{3}}(Pent-1-in) \\ & \_\,C{{H}_{3}}-C\equiv C-C{{H}_{2}}-C{{H}_{3}}(Pent-2-in) \\ & \_C{{H}_{3}}-\underset{\left| {} \right.}{\mathop{CH}}\,-C\equiv CH(3-Metylbut-1-in) \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\ \end{align} \)

\(\begin{align} & b)\,Pent-2-in:\,C{{H}_{3}}-C\equiv C-C{{H}_{2}}-C{{H}_{3}} \\ & 3-metylpent-1-in:\,C{{H}_{3}}-C{{H}_{2}}-\underset{\left| {} \right.}{\mathop{CH}}\,-C\equiv CH \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\, \\ & 2,5- đimetylhex-3-in:\,C{{H}_{3}}-\underset{\left| {} \right.}{\mathop{CH}}\,-C\equiv C-\underset{\left| {} \right.}{\mathop{CH}}\,-C{{H}_{3}} \\ & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{{H}_{3}} \\ \end{align} \)